Synthesis and mesomorphic properties of calamitic malonates and cyanoacetates tethered to 4-cyanobiphenyls

4-Cyano-1,1'-biphenyl derivatives bearing ω-hydroxyalkyl substituents were reacted with methyl 3-chloro-3-oxopropionate or cyanoacetic acid, giving liquid-crystalline linear malonates and cyanoacetates. These compounds formed monotropic nematic phases at 62 °C down to ambient temperature upon c...

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Bibliographic Details
Main Authors: Kress, Katharina C, Kaller, Martin, Axenov, Kirill V, Tussetschläger, Stefan, Laschat, Sabine
Format: Artigo
Language:Inglês
Published: Beilstein-Institut 2012
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3326613/
https://ncbi.nlm.nih.gov/pubmed/22509205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.40
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