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Spin Delocalization Over Type Zero Copper
Hard-ligand, high-potential copper sites have been characterized in double mutants of Pseudomonas aeruginosa azurin (C112D/M121X (X = L, F, I)). These sites feature a small A(zz)(Cu) splitting in the EPR spectrum together with enhanced electron transfer activity. Due to these unique properties these...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3322426/ https://ncbi.nlm.nih.gov/pubmed/22432748 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic202336m |
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