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Enantioselective Synthesis of (+)-Crocacin C. An Example of A Highly Challenging Mismatched Double Asymmetric δ-Stannylcrotylboration Reaction

[Image: see text] A concise, enantioselective synthesis of (+)-crocacin C is described, featuring a highly diastereoselective mismatched double asymmetric δ-stannylcrotylboration of the stereochemically demanding chiral aldehyde 9 with the bifunctional crotylborane reagent (S)-E-10. The total synthe...

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Bibliografiske detaljer
Main Authors: Chen, Ming, Roush, William R.
Format: Artigo
Sprog:Inglês
Udgivet: 2012
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3321065/
https://ncbi.nlm.nih.gov/pubmed/22409510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300476f
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