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Dynamics of a Supramolecular Capsule Assembly with Pyrene

Water-soluble octa-acid cavitands (OA) form dimeric capsules suitable for guest incorporation. Our studies reveal that the mechanism of pyrene (Py) binding follows the rapid (< 1 ms) formation of the Py•OA complex, followed by slower binding with the second OA. The dissociation of the capsular OA...

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Main Authors: Tang, Hao, de Oliveira, Carla Santos, Sonntag, Gage, Gibb, Corinne L.D., Gibb, Bruce C., Bohne, Cornelia
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3315598/
https://ncbi.nlm.nih.gov/pubmed/22417319
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja301278p
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