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Dynamics of a Supramolecular Capsule Assembly with Pyrene
Water-soluble octa-acid cavitands (OA) form dimeric capsules suitable for guest incorporation. Our studies reveal that the mechanism of pyrene (Py) binding follows the rapid (< 1 ms) formation of the Py•OA complex, followed by slower binding with the second OA. The dissociation of the capsular OA...
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Main Authors: | , , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2012
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3315598/ https://ncbi.nlm.nih.gov/pubmed/22417319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja301278p |
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