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Synthesis of 9-Substituted Xanthenes by the Condensation of Arynes with ortho-Hydroxychalcones

The reaction of o-(trimethylsilyl)aryl triflates, CsF, and o-hydroxychalcones affords a general and efficient way to prepare biologically interesting 9-substituted xanthenes. This chemistry presumably proceeds by tandem intermolecular nucleophilic attack of the phenoxide of the chalcone on the aryne...

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Hlavní autoři: Lu, Chun, Dubrovskiy, Anton V., Larock, Richard C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3314341/
https://ncbi.nlm.nih.gov/pubmed/22467977
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2012.02.072
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