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Enantioselective Total Synthesis of (S)-Bisoranjidiol, an Axially Chiral Bisanthraquinone

[Image: see text] The first enantioselective total synthesis of the bisanthraquinone (S)-bisoranjidiol and an unnatural regioisomer has been accomplished. Key features of the synthesis include the asymmetric oxidative biaryl coupling of a hindered 8-substituted 2-naphthol, selective para-quinone for...

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Detalhes bibliográficos
Main Authors: Podlesny, Erin E., Kozlowski, Marisa C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3306814/
https://ncbi.nlm.nih.gov/pubmed/22360604
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3001365
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