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Structure and reactivity of a mononuclear non-haem iron(III)–peroxo complex
Oxygen-containing mononuclear iron species—iron(III)–peroxo, iron(III)–hydroperoxo and iron(IV)–oxo—are key intermediates in the catalytic activation of dioxygen by iron-containing metalloenzymes(1–7). It has been difficult to generate synthetic analogues of these three active iron–oxygen species in...
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| Main Authors: | , , , , , , , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3306242/ https://ncbi.nlm.nih.gov/pubmed/22031443 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature10535 |
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