Structure and reactivity of a mononuclear non-haem iron(III)–peroxo complex

Oxygen-containing mononuclear iron species—iron(III)–peroxo, iron(III)–hydroperoxo and iron(IV)–oxo—are key intermediates in the catalytic activation of dioxygen by iron-containing metalloenzymes(1–7). It has been difficult to generate synthetic analogues of these three active iron–oxygen species in...

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Main Authors: Cho, Jaeheung, Jeon, Sujin, Wilson, Samuel A., Liu, Lei V., Kang, Eun A, Braymer, Joseph J., Lim, Mi Hee, Hedman, Britt, Hodgson, Keith O., Valentine, Joan Selverstone, Solomon, Edward I., Nam, Wonwoo
Format: Artigo
Jezik:Inglês
Izdano: 2011
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Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3306242/
https://ncbi.nlm.nih.gov/pubmed/22031443
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature10535
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