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{μ-2-[4-(Benzothia­zol-2-yl)benz­yl]-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′}bis­[tricarbonyl­iron(I)]

The title compound, [Fe(2)(C(16)H(14)N(2)S(3))(CO)(6)], was prepared as the biomimetic model for the active site of iron-only hydrogenase. The structure is similar to the diiron subsite of the iron-only hydrogenase active site, and contains a diiron-aza­dithiol­ate moiety in which a boat six-membere...

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Bibliografski detalji
Glavni autori: Gao, Shang, Duan, Qian, Jiang, Da-yong
Format: Artigo
Jezik:Inglês
Izdano: International Union of Crystallography 2012
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3297265/
https://ncbi.nlm.nih.gov/pubmed/22412455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536812006861
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