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Bis{μ-[4-(1,3-benzothiazol-2-yl)phenyl]methanethiolato-κ(4) S,S′:S,S′}bis[tricarbonyliron(I)](Fe—Fe)
The title compound, [Fe(2)(C(14)H(10)NS(2))(2)(CO)(6)], was synthesized as a structural and biochemical model for the active site of [FeFe]-hydrogenase. The bond lengths (Fe—Fe, Fe—S and Fe—C) and angles (C—Fe—Fe and Fe—S—Fe) are within expected ranges. The S⋯S distance [2.9069 (12) Å] and the dihed...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
International Union of Crystallography
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3297275/ https://ncbi.nlm.nih.gov/pubmed/22412465 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536812007581 |
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