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The identity of the exchangeable sulfur-containing ligand at the Mo(V) center of R160Q human sulfite oxidase

In our previous study of the fatal R160Q mutant of human sulfite oxidase (hSO) at low pH (Astashkin et al. J. Am. Chem. Soc. 2008, 130, 8471–8480) a new Mo(V) species, denoted “Species 1”, was observed at low pH values. Species 1 was ascribed to a six-coordinate Mo(V) center with an exchangeable ter...

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Detalhes bibliográficos
Main Authors: Klein, Eric L., Raitsimring, Arnold M., Astashkin, Andrei V., Rajapakshe, Asha, Johnson-Winters, Kayunta, Arnold, Anna R., Potapov, Alexei, Goldfarb, Daniella, Enemark, John H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3273672/
https://ncbi.nlm.nih.gov/pubmed/22225516
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic201643t
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