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Allenyl Azide Cycloaddition Chemistry: Application to the Total Synthesis of (±)-Meloscine
[Image: see text] The pentacyclic alkaloid (±)-meloscine was prepared in 19 steps through a reaction sequence that features a putative azatrimethylenemethane intermediate, generated through cascade cyclization of an allenyl azide substrate, to deliver the core azabicyclo[3.3.0]octadiene substructure...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3272129/ https://ncbi.nlm.nih.gov/pubmed/22242696 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol203463n |
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