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Mechanism of S-oxygenation by a cysteine dioxygenase model complex

In this work we present the first computational study on a biomimetic cysteine dioxygenase model complex, [Fe(II)(LN(3)S)](+) where LN(3)S is a tetradentate ligand with a bis(imino)pyridyl scaffold and a pendant arylthiolate group. The reaction mechanism of sulfur dioxygenation with O(2) was examine...

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Main Authors: Kumar, Devesh, Sastry, G. Narahari, Goldberg, David P., de Visser, Sam P.
Formato: Artigo
Idioma:Inglês
Publicado: 2011
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3267236/
https://ncbi.nlm.nih.gov/pubmed/22091701
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp208230g
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