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A [4 + 4] annulation strategy for the synthesis of eight-membered carbocycles based on intramolecular cycloadditions of conjugated enynes
A [4 + 4] annulation strategy for the synthesis of eight-membered carbocycles is reported that proceeds via a cascade involving two pericyclic processes. In the first step, the [4 + 2] cycloaddition of a conjugated enyne with an electron-deficient cyclobutene generates a strained six-membered cyclic...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3260789/ https://ncbi.nlm.nih.gov/pubmed/22267878 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.09.031 |
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