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Formal [2 + 2 + 2] Cycloaddition Strategy Based on an Intramolecular Propargylic Ene Reaction/Diels-Alder Cycloaddition Cascade

[Image: see text] A formal, metal-free, [2 + 2 + 2] cycloaddition strategy is described based on a cascade of two pericyclic processes. The first step involves an intramolecular propargylic ene reaction of a 1,6-diyne to generate a vinylallene, which then reacts in an inter-or intramolecular Diels-A...

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Detalhes bibliográficos
Main Authors: Robinson, Julia M., Sakai, Takeo, Okano, Katsuhiko, Kitawaki, Takafumi, Danheiser, Rick L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2924204/
https://ncbi.nlm.nih.gov/pubmed/20698669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1053829
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