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Mechanism of Radical-based Catalysis in the Reaction Catalyzed by Adenosylcobalamin-dependent Ornithine 4,5-Aminomutase
We report an analysis of the reaction mechanism of ornithine 4,5-aminomutase, an adenosylcobalamin (AdoCbl)- and pyridoxal l-phosphate (PLP)-dependent enzyme that catalyzes the 1,2-rearrangement of the terminal amino group of d-ornithine to generate (2R,4S)-2,4-diaminopentanoic acid. We show by stop...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Society for Biochemistry and Molecular Biology
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3259882/ https://ncbi.nlm.nih.gov/pubmed/18948256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M807911200 |
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