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Observation of the keto tautomer of D-fructose in D(2)O using (1)H NMR spectroscopy

D-Fructose was analysed by NMR spectroscopy and previously unidentified (1)H NMR resonances were assigned to the keto and α-pyranose tautomers. The full assignment of shifts for the various fructose tautomers enabled the use of (1)H NMR spectroscopy in studies of the mutarotation (5 – 25 °C) and tau...

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Autors principals: Barclay, Thomas, Ginic-Markovic, Milena, Johnston, Martin R., Cooper, Peter, Petrovsky, Nikolai
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3254704/
https://ncbi.nlm.nih.gov/pubmed/22129837
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.carres.2011.11.003
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