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The Cephalostatins 21. Synthesis of Bis-steroidal Pyrazine Rhamnosides(1)
The synthesis of bis-steroidal pyrazines derived from 3-oxo-11,21-dihydroxy-pregna- 4,17(20)-diene (4) and glycosylation of a D-ring side chain with α-L-rhamnose has been summarized. Rearrangment of steroidal pyrazine 10 to 14 was found to occur with boron triflouride etherate. Glycosylation of pyra...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3251514/ https://ncbi.nlm.nih.gov/pubmed/21899266 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/np200411p |
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