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Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways Involving Cu(II) and Cu(III) Species

Conjugated dienes can be diaminated at the internal and/or terminal double bonds using Cu(I) as catalyst and N,N-di-t-butyldiaziridinone (1) as nitrogen source. The regioselectivity is highly dependent upon the choice of Cu(I) catalyst and the substituents on diene substrates. The diamination likely...

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Bibliografske podrobnosti
Main Authors: Zhao, Baoguo, Peng, Xingao, Zhu, Yingguang, Ramirez, Thomas A., Cornwall, Richard G., Shi, Yian
Format: Artigo
Jezik:Inglês
Izdano: 2011
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3244543/
https://ncbi.nlm.nih.gov/pubmed/22081888
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207691a
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