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Synthetic and Mechanistic Studies on Pd(0)-Catalyzed Diamination of Conjugated Dienes
Various dienes and a triene can be regioselectively diaminated at the internal double bond with good yields and high diastereoselectivity using di-tert-butyldiaziridinone (5) as nitrogen source and Pd(PPh(3))(4) (1–10 mol%) as catalyst. Kinetic studies with (1)H NMR spectroscopy show that the diamin...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2846102/ https://ncbi.nlm.nih.gov/pubmed/20166669 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909459h |
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