Llwytho...

Synthetic and Mechanistic Studies on Pd(0)-Catalyzed Diamination of Conjugated Dienes

Various dienes and a triene can be regioselectively diaminated at the internal double bond with good yields and high diastereoselectivity using di-tert-butyldiaziridinone (5) as nitrogen source and Pd(PPh(3))(4) (1–10 mol%) as catalyst. Kinetic studies with (1)H NMR spectroscopy show that the diamin...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Zhao, Baoguo, Du, Haifeng, Cui, Sunliang, Shi, Yian
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2010
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2846102/
https://ncbi.nlm.nih.gov/pubmed/20166669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909459h
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