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Are C14-C15 single bond isomerizations of the retinal chromophore involved in the proton-pumping mechanism of bacteriorhodopsin?

Resonance Raman spectroscopy is used to examine the possibility that C14-C15 single bond isomerizations of the retinal prosthetic group are involved in the photochemical reactions of bacteriorhodopsin. Normal mode calculations show that the vibration that contains predominantly C14-C15 stretch chara...

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Sparad:
I publikationen:Proc Natl Acad Sci U S A
Huvudupphov: Smith, S O, Hornung, I, van der Steen, R, Pardoen, J A, Braiman, M S, Lugtenburg, J, Mathies, R A
Materialtyp: Artigo
Språk:Inglês
Utgiven: National Academy of Sciences 1986
Ämnen:
Research Article
Länkar:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC322991/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3006035/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.83.4.967
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