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Are C14-C15 single bond isomerizations of the retinal chromophore involved in the proton-pumping mechanism of bacteriorhodopsin?

Resonance Raman spectroscopy is used to examine the possibility that C14-C15 single bond isomerizations of the retinal prosthetic group are involved in the photochemical reactions of bacteriorhodopsin. Normal mode calculations show that the vibration that contains predominantly C14-C15 stretch chara...

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Detalhes bibliográficos
Main Authors: Smith, S O, Hornung, I, van der Steen, R, Pardoen, J A, Braiman, M S, Lugtenburg, J, Mathies, R A
Formato: Artigo
Idioma:Inglês
Publicado em: 1986
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC322991/
https://ncbi.nlm.nih.gov/pubmed/3006035
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