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Spectroscopic and Electronic Structure Studies Probing Covalency Contributions to C-H Bond Activation and Transition State Stabilization in Xanthine Oxidase
A detailed EPR and computational study of a key paramagnetic form of xanthine oxidase (XO) has been performed which serves as a basis for developing a valence bond description of C-H activation and transition state stabilization along the reaction coordinate with aldehyde substrates. EPR spectra of...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3222092/ https://ncbi.nlm.nih.gov/pubmed/21972782 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic201477n |
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