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Femtosecond dynamics coupled to chemical barrier crossing in a Born-Oppenheimer enzyme
Contributions of fast (femtosecond) dynamic motion to barrier crossing at enzyme catalytic sites is in dispute. Human purine nucleoside phosphorylase (PNP) forms a ribocation-like transition state in the phosphorolysis of purine nucleosides and fast protein motions have been proposed to participate...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
National Academy of Sciences
2011
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3219149/ https://ncbi.nlm.nih.gov/pubmed/22065757 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1114900108 |
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