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A direct conversion of benzylic and allylic alcohols to phosphonates

Benzyl phosphonate esters often serve as reagents in Horner-Wadsworth-Emmons reactions. In most cases, they can be prepared from benzylic alcohols via formation of the corresponding halide followed by an Arbuzov reaction. To identify a more direct synthesis of phosphonate esters, we have developed a...

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Autors principals: Barney, Rocky J., Richardson, Rebekah M., Wiemer, David F.
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3204863/
https://ncbi.nlm.nih.gov/pubmed/21405073
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo200137k
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