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Structure and Mechanism of the Diiron Benzoyl-Coenzyme A Epoxidase BoxB
The coenzyme A (CoA)-dependent aerobic benzoate metabolic pathway uses an unprecedented chemical strategy to overcome the high aromatic resonance energy by forming the non-aromatic 2,3-epoxybenzoyl-CoA. The crucial dearomatizing reaction is catalyzed by three enzymes, BoxABC, where BoxA is an NADPH-...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Society for Biochemistry and Molecular Biology
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3190730/ https://ncbi.nlm.nih.gov/pubmed/21632537 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M111.236893 |
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