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Thermodynamics of Boroxine Formation from the Aliphatic Boronic Acid Monomers R–B(OH)(2) (R = H, H(3)C, H(2)N, HO, and F): A Computational Investigation
Boroxines are the 6-membered cyclotrimeric dehydration products of organoboronic acids: 3 R– B(OH)(2) → R(3)B(3)O(3) + 3 H(2)O, and in recent years have emerged as a useful class of organoboron molecules with applications in organic synthesis both as reagents and catalysts, as structural components...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3154741/ https://ncbi.nlm.nih.gov/pubmed/21650154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp202409m |
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