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Total Synthesis of (–)-Nakadomarin A

[Image: see text] A concise diastereoselective total synthesis of (–)-nakadomarin A has been completed in 21 steps from D-pyroglutamic acid. Key steps include an enecarbamate Michael addition/furan-N-acyliminium ion cascade cyclization to provide the tetracyclic core, and ring-closing alkyne and alk...

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Detalhes bibliográficos
Main Authors: Nilson, Mark G., Funk, Raymond L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3151009/
https://ncbi.nlm.nih.gov/pubmed/20932022
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102079z
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