Synthesis, characterization and reactivity of carbohydrate platinum(IV) complexes with thioglycoside ligands

Reactions of fac-[PtMe(3)(4,4′-R(2)bpy)(Me(2)CO)][BF(4)] (R = H, 1a; (t)Bu, 1b) and fac-[PtMe(3)-(OAc-κ(2)O,O′)(Me(2)CO)] (2), respectively, with thioglycosides containing thioethyl (ch-SEt) and thioimidate (ch-STaz, Taz = thiazoline-2-yl) anomeric groups led to the formation of the carbohydrate pla...

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Main Authors: Vetter, Cornelia, Pornsuriyasak, Papapida, Schmidt, Jürgen, Rath, Nigam P., Rüffer, Tobias, Demchenko, Alexei V., Steinborn, Dirk
Formato: Artigo
Idioma:Inglês
Publicado: 2010
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3149867/
https://ncbi.nlm.nih.gov/pubmed/20517543
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b927058b
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