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Total Syntheses of Amphidinolides T1 and T4 via Catalytic, Stereoselective Reductive Macrocyclizations
Described in this work are total syntheses of amphidinolides T1 and T4 using two nickel-catalyzed reductive coupling reactions of alkynes, with an epoxide in one case (intermolecular) and with an aldehyde in another (intramolecular). The latter was used to effect a macrocyclization, form a C-C bond...
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| Main Authors: | , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2005
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3148192/ https://ncbi.nlm.nih.gov/pubmed/15783211 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja042733f |
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