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Nickel-Catalyzed Synthesis of Acrylamides from Alpha Olefins and Isocyanates
[Image: see text] The nickel(0)-catalyzed coupling of α-olefins and isocyanates proceeds in the presence of the N-heterocyclic carbene ligand IPr to provide α,β-unsaturated amides. Carbon-carbon bond formation occurs preferentially at the 2-position of the olefin. The N-tert-butyl amide products can...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3148187/ https://ncbi.nlm.nih.gov/pubmed/17269783 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol063111x |
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