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Exercising Regiocontrol in Palladium-Catalyzed Asymmetric Prenylations and Geranylation: Unifying Strategy Towards Flustramines A and B

Palladium-catalyzed asymmetric prenylation of oxindoles to selectively afford either the prenyl or the reverse prenyl product has been demonstrated. Control of regioselectivity in this transformation is governed by choice of ligand, solvent, and halide additive. The resulting prenylated and reverse...

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Detalhes bibliográficos
Main Authors: Trost, Barry M., Malhotra, Sushant, Chan, Walter H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3144703/
https://ncbi.nlm.nih.gov/pubmed/21520958
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2020873
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