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Effect of (13)C enrichment in the glassing matrix on dynamic nuclear polarization of [1-(13)C]pyruvate

Dimethyl sulfoxide (DMSO) can effectively form a glassy matrix necessary for dynamic nuclear polarization (DNP) experiments. We tested the effects of (13)C enrichment in DMSO on DNP of [1-(13)C]pyruvate doped with trityl radical OX063Me. We found that the polarization build-up time τ of pyruvate in...

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Bibliographic Details
Main Authors: Lumata, Lloyd, Kovacs, Zoltan, Malloy, Craig, Sherry, A. Dean, Merritt, Matthew
Format: Artigo
Language:Inglês
Published: 2011
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3144154/
https://ncbi.nlm.nih.gov/pubmed/21285486
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1088/0031-9155/56/5/N01
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