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Theoretical Study of the Mechanism of Oxoiron(IV) Formation from H(2)O(2) and a Nonheme Iron(II) Complex: O–O Cleavage Involving Proton-Coupled Electron Transfer
It has recently been shown that the nonheme oxoiron(IV) species supported by the 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane ligand (TMC) can be generated in near-quantitative yield by reacting [Fe(II)(TMC)(OTf)(2)] with a stoichiometric amount of H(2)O(2) in CH(3)CN in the presence of 2,...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3136038/ https://ncbi.nlm.nih.gov/pubmed/21678930 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic200522r |
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