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Pd(II)-Catalyzed Carbonylation of sp(3) C–H Bonds: A New Entry to 1,4-Dicarbonyl Compounds
Pd(II)-catalyzed β-C(sp(3))–H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))–H cleavage and insertion of CO into the resulting [Pd(II)–C(sp(3))] bond, intramolecular reductive amination gave the corresponding succinimides, which could be readily c...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3135760/ https://ncbi.nlm.nih.gov/pubmed/21082838 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108754f |
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