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Pd(II)-Catalyzed Carbonylation of sp(3) C–H Bonds: A New Entry to 1,4-Dicarbonyl Compounds

Pd(II)-catalyzed β-C(sp(3))–H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))–H cleavage and insertion of CO into the resulting [Pd(II)–C(sp(3))] bond, intramolecular reductive amination gave the corresponding succinimides, which could be readily c...

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Detalhes bibliográficos
Main Authors: Yoo, Eun Jeong, Wasa, Masayuki, Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3135760/
https://ncbi.nlm.nih.gov/pubmed/21082838
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108754f
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