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Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles

The selectivity of our previously described gold-catalyzed tandem reaction, 1,2-indole migration followed by aura-iso-Nazarov cyclization, of 3-propargylindoles bearing (hetero)aromatic substituents at both the propargylic and terminal positions, was reversed by the proper choice of the catalyst and...

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Detalhes bibliográficos
Main Authors: Álvarez, Estela, Miguel, Delia, García-García, Patricia, Fernández-Rodríguez, Manuel A, Rodríguez, Félix, Sanz, Roberto
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3135218/
https://ncbi.nlm.nih.gov/pubmed/21804873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.89
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