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Stable singlet carbenes as mimics for transition metal centers

This perspective summarizes recent results, which demonstrate that stable carbenes can activate small molecules (CO, H(2), NH(3) and P(4)) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive...

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Bibliographic Details
Main Authors: Martin, David, Soleilhavoup, Michele, Bertrand, Guy
Format: Artigo
Language:Inglês
Published: 2011
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3129870/
https://ncbi.nlm.nih.gov/pubmed/21743834
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C0SC00388C
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