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Stable singlet carbenes as mimics for transition metal centers
This perspective summarizes recent results, which demonstrate that stable carbenes can activate small molecules (CO, H(2), NH(3) and P(4)) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3129870/ https://ncbi.nlm.nih.gov/pubmed/21743834 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C0SC00388C |
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