Observation of Terahertz Vibrations in the Nitrogenase FeMo-cofactor via Femtosecond Pump Probe Spectroscopy

We have used Impulsive Coherent Vibrational Spectroscopy (ICVS) to study the FeMo-cofactor of nitrogenase from Azotobacter vinelandii as the extracted small molecule ‘FeMoco’. In the ICVS experiment, a 15 fs visible laser pulse pumps the sample to an excited electronic state, and a second <10 fs...

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Main Authors: Delfino, Ines, Cerullo, Giulio, Cannistraro, Salvatore, Manzoni, Cristian, Polli, Dario, Dapper, Christie, Newton, William E., Guo, Yisong, Cramer, Stephen P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3129498/
https://ncbi.nlm.nih.gov/pubmed/20411554
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200906787
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