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Low Frequency Dynamics of the Nitrogenase MoFe Protein via Femtosecond Pump Probe Spectroscopy – Observation of a Candidate Promoting Vibration

We have used femtosecond pump-probe spectroscopy (FPPS) to study the FeMo-cofactor within the nitrogenase (N(2)ase) MoFe protein from Azotobacter vinelandii. A sub-20-fs visible laser pulse was used to pump the sample to an excited electronic state, and a second sub-10-fs pulse was used to probe cha...

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Detalhes bibliográficos
Publicado no:J Inorg Biochem
Main Authors: Maiuri, Margherita, Delfino, Ines, Cerullo, Giulio, Manzoni, Cristian, Pelmenschikov, Vladimir, Guo, Yisong, Wang, Hongxin, Gee, Leland, Dapper, Christie H., Newton, William E., Cramer, Stephen P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4917305/
https://ncbi.nlm.nih.gov/pubmed/26343576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2015.07.005
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