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Spectroscopic and Computational Characterization of the Base-off Forms of Cob(II)alamin

The one-electron reduced form of vitamin B(12), cob(II)alamin (Co2+Cbl), is found in several essential human enzymes, including the cobalamin-dependent methionine synthase (MetH). In this work, experimentally validated electronic structure descriptions for two “base-off” Co(2+)Cbl species have been...

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Autores principales: Liptak, Matthew D., Fleischhacker, Angela S., Matthews, Rowena G., Telser, Joshua, Brunold, Thomas C.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3127260/
https://ncbi.nlm.nih.gov/pubmed/19298066
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp810136d
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