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Probing the Electronic Demands of Transmetalation in the Palladium-Catalyzed Cross-Coupling of Arylsilanolates

The electronic characteristics of coupling partners in the transmetalation step for the cross-coupling reaction of arylsilanolates have been investigated. The ability to interrogate the transmetalation event by in situ preparation of the arylpalladium(II) silanolate intermediate has enabled a Hammet...

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Bibliografski detalji
Glavni autori: Denmark, Scott E., Smith, Russell C., Chang, Wen-Tau T.
Format: Artigo
Jezik:Inglês
Izdano: 2011
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3126151/
https://ncbi.nlm.nih.gov/pubmed/21731114
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.03.066
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