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A new approach to fused furan ring systems and benzofurans: Intramolecular cyclization reactions of unsaturated acyloxy sulfone derivatives

Unsaturated acyloxy sulfones 3 undergo intramolecular cyclization upon deprotonation with LHMDS in THF. Dehydration and double bond isomerization of the products upon exposure to acid, gave the fused ring furans, 4, in good yields. This strategy could be readily adapted to 12 from the cyclization re...

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Detalhes bibliográficos
Main Authors: Liu, Yuan, Jacobs, Hollie K., Gopalan, Aravamudan S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3126094/
https://ncbi.nlm.nih.gov/pubmed/21731117
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2011.03.120
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