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Palladium(0)-Catalyzed Arylative Dearomatization of Phenols

The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontr...

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Bibliografiske detaljer
Main Authors: Rousseaux, Sophie, García-Fortanet, Jorge, Del Aguila Sanchez, Miguel Angel, Buchwald, Stephen L.
Format: Artigo
Sprog:Inglês
Udgivet: 2011
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3124856/
https://ncbi.nlm.nih.gov/pubmed/21612204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja203644q
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