Conversion of Fatty Aldehydes to Alka(e)nes and Formate by a Cyanobacterial Aldehyde Decarbonylase: Cryptic Redox by an Unusual Di-metal Oxygenase

Cyanobacterial aldehyde decarbonylase (AD) catalyzes conversion of fatty aldehydes (R-CHO) to alka(e)nes (R-H) and formate. Curiously, although this reaction appears to be redox-neutral and formally hydrolytic, AD has a ferritin-like protein architecture and a carboxylate-bridged di-metal cofactor t...

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Hauptverfasser: Li, Ning, Nørgaard, Hanne, Warui, Douglas M., Booker, Squire J., Krebs, Carsten, Bollinger, J. Martin
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2011
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3113487/
https://ncbi.nlm.nih.gov/pubmed/21462983
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2013517
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