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Probing the Mechanism of Cyanobacterial Aldehyde Decarbonylase Using a Cyclopropyl Aldehyde

Cyanobacterial aldehyde decarbonylase (cAD) is a non-heme di-iron oxygenase that catalyzes the conversion of fatty aldehydes to alkanes and formate. The mechanism of this chemically unusual reaction is poorly understood. We have investigated the mechanism of C1-C2 bond cleavage by cAD using a fatty...

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Autores principales: Paul, Bishwajit, Das, Debasis, Ellington, Benjamin, Marsh, E. Neil G.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2013
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3651851/
https://ncbi.nlm.nih.gov/pubmed/23514600
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3115949
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