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COMPARATIVE ASSESSMENT OF THE COMPOSITION AND CHARGE STATE OF NITROGENASE FeMo-COFACTOR

A significant limitation in our understanding of the molecular mechanism of biological nitrogen fixation is the uncertain composition of the FeMo-cofactor (FeMo-co) of nitrogenase. In this study we present a systematic, density functional theory-based evaluation of spin coupling schemes, iron oxidat...

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Detalhes bibliográficos
Main Authors: Harris, Travis V., Szilagyi, Robert K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3105220/
https://ncbi.nlm.nih.gov/pubmed/21545160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic102446n
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