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Direct Synthesis of Diastereomerically Pure Glycosyl Sulfonium Salts

[Image: see text] It is reported that stable glycosyl sulfonium salts can be generated via direct anomeric S-methylation of ethylthio glycosides. Mechanistically, this pathway represents the first step in the activation of thioglycosides for glycosidation, however, it can further allow for the synth...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Mydock, Laurel K., Kamat, Medha N., Demchenko, Alexei V.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2011
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3104671/
https://ncbi.nlm.nih.gov/pubmed/21563800
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2009818
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