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Direct Synthesis of Diastereomerically Pure Glycosyl Sulfonium Salts
[Image: see text] It is reported that stable glycosyl sulfonium salts can be generated via direct anomeric S-methylation of ethylthio glycosides. Mechanistically, this pathway represents the first step in the activation of thioglycosides for glycosidation, however, it can further allow for the synth...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3104671/ https://ncbi.nlm.nih.gov/pubmed/21563800 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2009818 |
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