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Direct Synthesis of Diastereomerically Pure Glycosyl Sulfonium Salts

[Image: see text] It is reported that stable glycosyl sulfonium salts can be generated via direct anomeric S-methylation of ethylthio glycosides. Mechanistically, this pathway represents the first step in the activation of thioglycosides for glycosidation, however, it can further allow for the synth...

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Hlavní autoři: Mydock, Laurel K., Kamat, Medha N., Demchenko, Alexei V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3104671/
https://ncbi.nlm.nih.gov/pubmed/21563800
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2009818
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