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Quenched phosphorescence as alternative detection mode in the chiral separation of methotrexate by electrokinetic chromatography

Quenched phosphorescence was used, for the first time, as detection mode in the chiral separation of methotrexate (MTX) enantiomers by electrokinetic chromatography. The detection is based on dynamic quenching of the strong emission of the phosphorophore 1-bromo-4-naphthalene sulfonic acid (BrNS) by...

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Detalhes bibliográficos
Main Authors: Castro-Puyana, María, Lammers, Ivonne, Buijs, Joost, Gooijer, Cees, Ariese, Freek
Formato: Artigo
Idioma:Inglês
Publicado em: Springer-Verlag 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3102850/
https://ncbi.nlm.nih.gov/pubmed/21499966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00216-011-4991-6
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